Friends of a man extradited to Italy on Tuesday on people smuggling charges say police have the wrong man.
Prosecutors believe Mered Medhanie, known as The General, is at the heart of the operation to smuggle migrants from Africa to Europe.
An Eritrean man authorities say is Mr Mered was held in Sudan in May and flown to Rome on Tuesday.
But the man's friends told the BBC there had been a case of mistaken identity and he was innocent.
He was named by friends as Mered Tesfamariam.
A spokesman for Britain's National Crime Agency (NCA), that was involved in the operation, told the Press Association they were "liaising with our partners".
It added: "This is a complex multi-partner operation and it is too soon to speculate about these claims."
An Italian police official told the BBC that he was unaware of any investigation into the identity of the suspected smuggler. The BBC understands that the Italian police still believe they have the right person.
The NCA said it had tracked the suspect down to an address in Khartoum, where he was then arrested.
Images of him arriving in Rome were distributed by Italian police on Wednesday.
The BBC spoke to one man, Hermon Berhe, who lives in Ethiopia and said he grew up in Eritrea with the man shown in the pictures.
"I don't think he has any bone in his body which can involve such kind of things," he said. "He is a loving, friendly and kind person."
Another Eritrean man told the BBC's Will Ross he recently shared a house in Sudan with the man who was arrested.
Meron Estefanos, a Swedish-Eritrean journalist who interviewed Mr Mered last year, told Swedish media the man in the images was not him, but was instead a 28-year-old man with the same name.
"He's just a refugee who was in Khartoum, poor guy," she told aftonbladet newspaper.
Italian news agency Ansa said Mr Mered was accused of being "the leader and organiser of one of the largest criminal groups operating between central Africa and Libya".
Prosecutors accuse Mr Mered of running the network alongside an Ethiopian accomplice, who is still at large.
The two men are accused of buying up kidnapped migrants from other gangs and sending those migrants on barely seaworthy ships across the Mediterranean towards Europe.
Known as "The General", as he styled himself on late Libyan leader Col Muammar Gaddafi, Mr Mered is also said to have driven around in a tank and boasted: "Nobody is stronger than me."
The NCA says Mr Mered is thought to have arranged the transit of a boat that sank near the Italian island of Lampedusa in October 2013.
At least 359 migrants died when the boat, travelling from Libya, capsized. Most were from Eritrea and Somalia.
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